Hello,
no, it cannot work this way. Encrypted files are always different due to salting. Their hashes cannot be compared.
The only way to verify the files is to download them and decrypt/decompress them.
You can use "Binary Comparison" on the tab sheet "Comparison" -> "More" to do this. Use the checkmark "Remember Results" to avoid verifying the same file again if the comparison job is started another time.
If you would like to verify only a subset, to save time and bandwidth, you can use a filter such as File Age: less than 100 days.
As an alternative, you can right-click a profile and choose "Test Backup Integrity". This will also download and unpack the files, but it won't compare them to the originals. The process might be a little faster, and verification against the checksums embedded in compressed archives is usually sufficient.